Hi Eric,
Use the [[Join()]] function token. Because of the way ASP.NET works, it's not possible to simply combine a field token with text in an attribute. The JOIN token makes that possible. You can find the details on how to use it in the help file under Function Tokens.
So, your tag would be re-written as such:
<xmod:DetailImage AlternateText="ViewProperty" ImageUrl='[[Join("/Portals/0/propertyimages/thm_{0}", [[Pohoto01]])]]'>
<Parameter name="PropertyID" Value='[[PropertyID]]' />
</xmod:DetailImage>
Best,
Kelly